Hello and welcome
Okay, first:
You need to take your time and be precise. The eyes arn't really circular, you should try using the marque tools when your painting, it will make your job a lot easier and a lot more precise (Good job on the teeth but not as well on the eyes, did you start with the teeth?)
Again, you've forgotten some grey paint around the mouth, patience again
Did you follow tutorials or was it just mind made?
I, strongly suggest you follow tutorials or if you can get a teacher, even better. That way, yo'll be going deeper and deeper into photoshop, learning filters, layers, blending modes and so on.
Anyways, I see some potential, keep it up!